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Depending on the brand and how the peanut butter separates, you might have to add more flour or glycerin to get the right texture.
What you are looking for is a silky texture that holds its shape but is still a little sticky so the dog will swallow it rather than chew it. You want to be able to shape it around a pill.
Things to remember; don't make too much as it will spoil and keep what you do make in the fridge. If you have more than one dog, start by giving a small piece to each dog then administer the pill.